The specific rotation of (R) carvone is (+) 61°. The optical rotation of a sample of a mixture of R &S carvone is measured as (-) 23°. Which enantiomer is in excess and what is its enantiomeric excess? What are the percentages of (R) - & (S) - carvone in the sample​

Answers

Answer 1

Answer:

See explanation

Explanation:

% optical purity = specific rotation of mixture/specific rotation of pure enantiomer  * 100/1

specific rotation of mixture = 23°

specific rotation of pure enantiomer = 61°

Hence;

% optical purity = 23/61 * 100 = 38 %

More abundant enantiomer = 100% - 38 % = 62%

Hence the pure  (S) carvone is (-) 62° is the more abundant enantiomer.

Enantiomeric excess = 62 - 50/50 * 100 = 24%

Hence

(R) - carvone  =  38 %

(S) - carvone = 62%

Answer 2

Answer:

Explanation:

ee= -23/-61 × 100= 38%

S + R = 100%

S - R = 38%

Solve simultaneously;

S= 69% ( excess)

R= 100-69= 31%


Related Questions

Which specialized structures allow dolphins to breathe?
A. Watertight eggs
O B. Gills
C. Lungs
D. Milk-producing glands

Answers

Answer:

lungs

Explanation:

they don't have gills, and the milk producing glands and watertight eggs have nothing to do with it

Answer:

lungs

Explanation:

dolphins are mammals not fish

Plzzzzzzz helpppppppppp

Answers

Answer:

False

Explanation:

A phenotype is physical characteristics, like eye color, and genotype is the code (tt, Tt, TT, that sort of thing) for it. A genotype can be dominant or recessive, dominant is capita, recessive is lowercase.

Question 32. If scientist make an observation that does not agree with an accepted scientific theory, the scientists should
PLEASE HURRY

Answers

Answer:

I would say A.

Explanation:

explain how density can be used as a conversion factor to convert the volume of an object to the mass of the object, and vice versa ​

Answers

The density of a substance tells you the mass of exactly one unit of volume of that substance. This essentially means that density can be used as a conversion factor to go from the mass of a sample to the volume it occupies, or vice versa. This means that every milliliter of the substance has a total mass of 1.50 grams

Density is defined as the mass per unit volume it means that mass present in 1 meter cube. The S.I unit of density is kg/m^3 and in C.G.S and it is gram/cm^3

What is density?

Density is defined as the mass per unit volume it means that mass present in 1 meter cube. The S.I unit of density is kg/m^3 and in C.G.S and it is gram/cm^3

In above statement we can understand that density, mass, and volume all are convert to each other it means that if we know any two variable then third one will be calculated easily.

Mathematically,

Formula for density will be as mentioned below:-

Density = Mass/Volume.

From above formula we can calculate mass which is as follows:-

Mass = Volume × Density.

S.I unit of mass is kilograms and C.G.S unit is gram.

And similarly we can calculate the volume which is equal to as follows:-

Volume = mass / density.

S.I unit of volume is meter cube and C.G.S unit is cubic centimeter.

So, we can say that mass, volume and density all are dependent to each other and if any two is known we can easily calculate the third one.

Therefore, Density is defined as the mass per unit volume it means that mass present in 1 meter cube. The S.I unit of density is kg/m^3 and in C.G.S and it is gram/cm^3.

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The element belongs to the p-block. It exhibits some characteristics of metals and some of nonmetals. It is a solid at room temperature. It contains 3d electrons, but not 4d electrons. It is also known NOT to have chemical properties similar to those of nitrogen. The element must be

Answers

Answer:

Arsenic

Explanation:

From the introduction given in the question, the element we are considering must be a member of group 15 because of its similarity to nitrogen.

We were also told that it exhibits the characteristics of metals and some nonmetals hence the element is a metalloid.

Lastly we were told that it contains 3d but not 4d electrons. This has ruled out  antimony. Our only element standing now is arsenic!

The electronic configuration of arsenic is; [Ar] 3d¹⁰ 4s² 4p³. Hence the correct answer is arsenic.

WHAT IS THE ABILITY OF A SUBSTANCE TO BE DISSOLVED

Answers

Answer:

Solubility

Explanation:

Which location is more likely to experience rain?

location a 67%
location b 23%
location c 45%
location d 88%​

Answers

Location D. bc it’s the highest percentage at 88% then it would be A,C,B

If a solution containing 117.63 g of silver chlorate is allowed to react completely with a solution containing 10.23 g of lithium bromide, how many grams of solid precipitate will be formed

Answers

Answer:

18.8 g

Explanation:

The equation of the reaction is;

AgClO3(aq) + LiBr(aq)------>LiClO3(aq) + AgBr(s)

Number of moles of AgClO3 = 117.63 g/191.32 g/mol = 0.6 moles

Number of moles of LiBr = 10.23 g/86.845 g/mol  = 0.1 moles

Since the molar ratio is 1:1, LiBr is the limiting reactant

Molar mass of solid AgBr = 187.77 g/mol

Mass of precipitate formed = 0.1 moles * 187.77 g/mol

Mass of precipitate formed = 18.8 g

If in a solution reaction between 117.63 g of silver chlorate and 10.23 g of lithium bromide takes place then, 18.8 grams of solid precipitate will be formed.

What is limiting reagent?

In any chemical reaction limiting reagent is that reagent whose moles are present in less quantity as compared to the other reagent, is responsible for the formation of product.

Given chemical reaction is:
AgClO₃(aq) + LiBr(aq) → LiClO₃(aq) + AgBr(s)

Moles (n) will ce calculated as:

n = W/M, where

W = given mass

M = molar mass

Moles of AgClO₃ = 117.63g / 191.32g/mol = 0.6 moles

Moles of LiBr = 10.23g / 86.845g/mol  = 0.1 moles

In this reaction LiBr is the limiting reagent and formation of product depends on this.

From the stoichiometry of the reaction it is clear that:
0.1 mole of LiBr = produce 0.1 mole of AgBr

Mass of AgBr = (0.1mol)(187.77g/mol) = 18.8 g

Hence mass of AgBr is 18.8 g.

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Which evidence is an indication that a chemical reaction has occurred?
A) melting of a substance
B) formation of a gas
C) boiling of a substance
D) freezing of a substance

Answers

Formation of gas is an evidence that a chemical reaction has occurred.

What are the characteristics of chemical reaction?

The characteristics of chemical reaction are as follows:

1) Color change- The change in color of reactants when it is converted to products indicate that the reaction has taken place.

2)Evolution of gas-In some reactions , a gas is evolved indicating occurrence of chemical reaction.

3)Formation of precipitate- In some chemical reactions, an insoluble solid called as precipitate is obtained which is an indication that a chemical reaction has taken place.

4)Change in energy- In some cases of chemical reactions, there is a change in energy which is observed indicating occurrence of chemical reaction.

As the formation of gas is the characteristic of chemical reaction it serves as an indication  for occurrence of chemical reaction.

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Enter the chemical formula of a binary molecular compound of hydrogen and a Group 6A element that can reasonably be expected to be more acidic in aqueous solution than , e.g. have a larger .

Answers

The question is incomplete, the complete question is;

Enter the chemical formula of a binary molecular compound of hydrogen and a Group 6A element that can reasonably be expected to be more acidic in aqueous solution than H2S , e.g. have a larger Ka.

Answer:

H2Se

Explanation:

The acidity and extent of acid dissociation (shown by Ka value) depends on the nature of the bond between hydrogen and the group 6A element.

If we compare the H-S bond and the H-Se bond, we will discover that the H-Se bond is longer, weaker and breaks more easily than the H-S bond. As a result of this, H2Se is more acidic than H2S.

There are three isotopes of X element (X):
X-17 isotope: atomic mass17.2 amu, abundance:78.99%
X-18isotope: atomic mass 18.1 amu, abundance 10.00%
X-19isotope: atomic mass:19.1 amu, abundance: 11.01%
Calculate the average atomic mass of X.

Answers

Explanation:

hope it will help friends

The molar mass-of H2O is 18.02 gram /mol. How many moles are present in 3.33 x 1024 molecules of
H2O?
Select one:
a. 9.97 moles H20
b. 99.7 moles H2O
c. 2.00 x 1048 moles H20
d. 5.53 moles H20

Answers

Answer

5.53moles

Explanation:

Given parameters

Number of molecules = 3.33 x 10²⁴

Unknown

Number of moles = ?

Solution

A mole of a substance contains the Avogadro's number of particles.

1 mole of a substance = 6.02 x 10²³

So, 3.33 x 10²⁴ molecules will contain;

3.33 x 10²⁴ / 6.02 x 10²³

= 5.53moles

What mass of NaOH is needed to make 500mL of 4M solution

Answers

Answer:

80.0 grams NaOH

Explanation:

500 mL = 0.500 L

M = moles / liters

4 M =    x moles / 0.500 L

Multiply both sides by 0.500 L

2 moles = x

Convert moles to grams

2 moles NaOH x (39.998 grams NaOH / 1 mole) = 80.0 grams NaOH

In the nitrite ion (NO2-), __________. A) both bonds are single bonds B) both bonds are double bonds C) one bond is a double bond and the other is a single bond D) both bonds are the same E) there are 20 valence electrons

Answers

Answer:

B) Both bonds are double bonds

Explanation:

For nitrite ion, oxygen reacts with nitrogen oxide which is joined by a double bond to form nitrite ion.

Now, nitrite ion cannot have an expanded octet and thus both bonds will be the same with each bond being stronger and shorter than a single bond but they will be longer and weaker than a double bond.

PLZ HELP WILL GIVE 40 POINTS PLEASE

Answers

Answer:

A?

Explanation:

Denmark is characterized as temperature as a region . the winters typicky experience frequent snowfall and low temperatures. in contrast, the summers are typically mild. is the sentence talking about climate, whether, topography or atmosphere​

Answers

Its climate

because the paragraph talks about how the weather changes during the seasons in Denmark

During a lunar eclipse, what occurs? *

A. The Sun's shadow falls on the Moon.
B. The Moon's shadow falls on the Earth.
C. The Earth's shadow falls on the Moon.
D. The Moon's shadow falls on the Sun

Half of the Earth is dark. What is the dark half of Earth experiencing? *

A. A lunar eclipse
B. A solar eclipse
C. A power outage
D. Nighttime

A lunar eclipse in which the Moon lies completely in the Earth’s umbra is called a total lunar eclipse. In a penumbral lunar eclipse, the Moon lies partially in the penumbra. *

A. true
B. False

Each lunar cycle has one full moon, in which the relative positions of Earth, the sun, and the moon form in a straight line. Which list represents the position of Earth, the sun, and the moon during a full moon? *

A. Earth, sun, moon
B. sun, moon, Earth
C. moon, sun, Earth
D. sun, Earth, moon

Answers

Answer:

Lunar eclipse answer is

b

Ibuprofen (aka ADVIL) is a weak acid with a pKa of 4.9. It is absorbed through the stomach and the small intestine as a function of polarity - charged and very polar molecules are absorbed slowly; neutral hydrophobic molecules absorb quickly. If the stomach pH is about 1.5 and the small intestine pH is about 6, where (and why) will more ibuprofen be absorbed into the bloodstream

Answers

Answer:

Explanation:

There will be absorption of more ibuprofen in the stomach due to the fact that  it will be uncharged because the pH is lower than the pKa.

The molecular formula for Ibuprofen is: C₁₃H₁₈O₂

The IUPAC name is:

(RS)-2-(4-(2-methylpropyl)phenyl)propanoic acid

From the attached image, we will see the structural formula of Ibuprofen.

What is the frequency of light whose wavelength is 6.33 x 10-7m?

Answers

Answer:

the frequency of light is

[tex]4.74 \times {10}^{14} [/tex]

Explanation:

from v = λf

speed of light in air, v = 3.0*10^8ms^-1

If an instant pot has an internal pressure of 191.0 kPa, temperature of 750.0 K and a volume of 6.5 L, how many moles of gas would be contained inside the instant pot?

Answers

Answer:

0.200 mol.

Explanation:

Hello!

In this case, since this case is considered an ideal one (no intermolecular interactions), we can use the following equation:

[tex]PV=nRT[/tex]

Thus, since we know the pressure, temperature and volume, we are able to compute the moles shown below:

[tex]n=\frac{PV}{RT} =\frac{191kPa*\frac{1000Pa}{1kPa} *6.5L*\frac{1m^3}{1000L} }{8.314\frac{Pa*m^3}{mol*K}*750.0K}\\\\n=0.200mol[/tex]

Best regards!

PLZ HELP 40 POINTS PLEASEEEEEE

Answers

Answer:

should be A

Explanation:

A4.5 g metal sample decreases in temperature from 48°C to 25°C when 68.5
of heat is removed from it. Calculate the specific heat capacity of the metal.

Answers

Answer:

[tex]C=0.662\frac{J}{g\°C}[/tex]

Explanation:

Hello!

In this case, since the heat removal when cooling down a body is computed via:

[tex]Q=mC\Delta T[/tex]

Given the removed heat, mass and temperature change, we solve for the heat capacity of the metal as shown below:

[tex]C=\frac{Q}{m\Delta T}[/tex]

Thus, by plugging in we obtain:

[tex]C=\frac{-68.5J}{4.5g*(25-48)\°C} \\\\C=0.662\frac{J}{g\°C}[/tex]

Best regards!

Which of these can be found in a plant cell but not in an animal cell?
A.) chromosome
B.)nucleus
C.)chloroplast
D.)cell membrane


i would really like it if u could help me out with this. please and thank u :)

Answers

Answer:

C.)chloroplast

Explanation:

The plant cell has a cell wall, chloroplasts, plastids, and a central vacuole—structures not found in animal cells. Plant cells do not have lysosomes or centrosomes.

Breathing air that contains 4.0% by volume CO2 over time causes rapid breathing, throbbing headache, and nausea, among other symptoms. what is the concentration of co2 in such air in terms of mol percentage

Answers

Answer:

1 mole of any ideal gas occupies the same volume as one mole of any other ideal gas under the same conditions of temperature and pressure.So 1 L CO2 has same number of moles as 1 L O2 and 1 L N2 etc.This means that, assuming all the gases in air are ideal gases, if CO2 is 4.0 % by volume then it is also 4.0 % by moles, because a volume of each gas has the same number of moles.

Explanation:

Pure water and pure salt are poor conductors of electricity. When salt is dissolved in water, the resulting solution conducts electricity well. Which statement explains why this occurs with these substances?

The process of dissolving makes the electrons in their atoms free to move

The process of dissolving makes the atoms in them free to move

The process of dissolving makes the electrons in their atoms more closely bound

The process of dissolving makes the atoms in them more closely bound to each other

Answers

Answer:the process of dissovlving makes the ecectrons in their atoms more closely bound

Explanation:

thats what my lesson said

The solution of water and salt are good conductor of electricity because the process of dissolving makes the electrons in their atoms free to move.

The correct option is (A).

What makes a solution of water and salt a good conductor?

Pure water and salt are bad conductor of electricity.

But the solution of water and salt is a good conductor because when a salt's dissociated it's ions are free to move about in solution when it dissolves, allowing a charge to flow freely.

Because it includes ions, the resulting solution will conduct electricity.

Thus, option (A) the process of dissolving makes the electrons in their atoms free to move, that's why the solution of water and salt are good conductor of electricity.

Learn more about solution, here:

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Which of the following converts mechanical energy to electrical energy?
O A. An electric generator
O B. A loudspeaker
O C. An electromagnet
O D. An electric motor

Answers

Answer:

an electrical generator

At what temperature can 10g of Cez(SO4)3 be dissolved in 100g of water?
A.10
B.20
C.60
D.40

Answers

I would say the answer is a
The answer to this question is A

A sample of carbon monoxide gas occupies 3.20 L at
125 °C. At what temperature will the gas occupy a
volume of 1.54 L if the pressure remains constant?​

Answers

The final temperature : 191.54 K = -81.46 °C

Further explanation

Given

V₁=3.2 L

T₁ = 125 +273 = 398 K

V₂=1.54 L

Required

The final temperature(T₂)

Solution

Charles's Law  

When the gas pressure is kept constant, the gas volume is proportional to the temperature  

[tex]\tt \dfrac{V_1}{T_1}=\dfrac{V_2}{T_2}[/tex]

T₂=(V₂T₁)/V₁

T₂=(1.54 x 398)/3.2

T₂=191.54 K = -81.46 °C

***Question in photo***

Is the entropy positive or negative in this question?

Answers

Answer:

Enthalpy change is negative

Entropy change is Positive

Explanation:

A drawback of the space shuttle was

Answers

Answer:

The space shuttle was the result of committee compromise and political expediency. It was never the best design. It takes off like a rocket (and blows up like one on occasion) and lands like a plane (or rather, it lands like a brick with control surfaces).

Explanation:

Answer:

The space shuttle was the result of committee compromise and political expediency. In 1990 Scientists decided to launch the space shuttle. It was never the best design. It takes off like a rocket (and blows up like one on occasion) and lands like a plane (or rather, it lands like a brick with control surfaces).

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