Identify the most acidic hydrogens in each of the following molecules. Give the structure of the enolate ion arising from deprotonation. (a) Acetaldehyde; (b) propanal; (c) acetone; (d) 4-heptanone; (e) cyclopentanone.

Answers

Answer 1

Answer:

See explanation below (Brainlist please)

Explanation:

First of all, we need to understand what is an acidic hydrogen.

An acidic hydrogen, is the atom of hydrogen which is more propense to undergo an acid base reaction, and form a stable ion or molecule in the process.

In other words, is the hydrogen that is more vulnerable to get substracted in an acid base reaction to form another compound.

Knowing this information, gives us an idea of how a molecule can be formed and which kind of compound is formed.

Now, in this question, we have 5 molecules. Each of them is either a ketone or aldehyde, so this mean that we have the carbonile group (C = O), which means that is easier to identify the acidic hydrogen. This is because the Carbonile group is an attractor group, so, it will attract the charges by inductive effect (in some cases by resonance), and the molecule is more stable.

This can be shown by drawing the enolate ion that is formed once the molecule undergo the acid base reaction. As it's an enolate form that we are looking for, then it means that the ketone or aldehyde is undergoing an electrofilic attack with a base. This base will substract the most acidic hydrogen to form a better and stable enolate. The acidic hydrogen and the enolate form can be seen in the attached picture.

a) In the case of acetaldehyde, the most acidic will be the hydrogen of carbon 2, because the hydrogen from the carbonile, once it's substracted, the charge of the carbon cannot be stabilized by resonance. Carbon 2 hydrogens, can do this job easily.

b) Propanal happens something similar to acetaldehyde, the terminal hydrogen cannot be substracted, and carbon 3, once the hydrogen is gone, the negative charge cannot be stabilized by resonance, so hydrogens of carbon 2 can do this.

c) in the case of acetone, is easier to look because we only have the C = O between two methyl group, so you can use either carbon 1 or 3 to do the job.

d) 4 heptanone the most acidic hydrogen would be carbon 3 or 5, because they are closer to the C=O and the ion can be stabilized by resonance.

e) Finally in ciclopentanone, the most acidic hydrogen would be carbon 2 or 5.

See picture for a better understanding.

Hope it helps.

Identify The Most Acidic Hydrogens In Each Of The Following Molecules. Give The Structure Of The Enolate

Related Questions

Calculate the molar mass of adrenaline (C9H13NO3C9H13NO3), a hormone responsible for regulating heart rate and other functions of the sympathetic nervous system. Express your answer to five significant figures.

Answers

Answer:

[tex]M_{C_9H_{13}NO_3}=183.23g/mol[/tex]

Explanation:

Hello!

In this case, since the molar mass of a chemical compound is computed by averaging the atomic mass of each element in the molecule and the amount of atoms; which in this case there are 9 carbon atoms, 13 hydrogen atoms, 1 nitrogen atom and 3 oxygen atoms; thus, we compute the average as shown below:

[tex]M_{C_9H_{13}NO_3}=m_C*9+m_H*13+m_N+m_O*3[/tex]

Now, we plug in the atomic masses to obtain:

[tex]M_{C_9H_{13}NO_3}=12.01*9+1.01*13+14.01+16.00*3\\\\M_{C_9H_{13}NO_3}=183.23g/mol[/tex]

Best regards!

A 1.00-L flask was filled with 2.00 moles of gaseous and 2.00 moles of gaseous and heated. After equilibrium was reached, it was found that 1.21 moles of gaseous was present. Assume that the reaction

SO2 + NO2 ⇌ SO3 + NO

occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reaction.

Answers

Answer:

2.35

Explanation:

A 1.00-L flask was filled with 2.00 moles of gaseous SO₂ and 2.00 moles of gaseous NO₂ and heated. After equilibrium was reached, it was found that 1.21 moles of gaseous NO was present. Assume that the reaction

SO₂ + NO₂ ⇌ SO₃ + NO

occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reaction.

Step 1: Calculate the molar concentrations

Since the reaction takes place in a 1.00 L flask, the molar concentrations are:

[SO₂]i = 2.00 M

[NO₂]i = 2.00 M

[NO]eq = 1.21 M

Step 2: Make an ICE chart

        SO₂ + NO₂ ⇌ SO₃ + NO

I       2.00   2.00       0        0

C        -x       -x         +x       +x

E    2.00-x  2.00-x    x         x

Step 3: Calculate the concentrations at equilibrium

The concentration of NO at equilibrium is 1.21 M. Then, x = 1.21.

[SO₂]eq = 2.00-1.21 = 0.79 M

[NO₂]eq = 2.00-1.21 = 0.79 M

[SO₃]eq = x = 1.21 M

[NO]eq = x = 1.21 M

Step 4: Calculate the value of the equilibrium constant, K, for this reaction

K = [SO₃] × [NO]/[SO₂] × [NO₂]

K = 1.21²/0.79² = 2.35

5. What does the symbol in the picture represent? *
A.Battery
B.Resistor
C.Wire
D.Bulb

Answers

Battery is the answer

What is The Magnus Effect/Force? Explain.

Answers

Answer:

dk

Explanation:

How many milliliters of sterile water for injection should be added to a vial containing 5 mg/mL of a drug to prepare a solution containing 1.5 mg/mL of the drug

Answers

Answer:

7mL of sterile water is the initial amount of the concentrated solution is 3mL

Explanation:

In this problem, the vial must be diluted from 5mg/mL to 1.5mg/mL, that means the solution must be diluted:

5mg/mL / 1.5mg/mL = 3.33 times

If the initial amount of the drug in the vial is 3mL, the final volume must be:

10mL

That means the volume of water that should be added is:

10mL - 3mL:

7mL of sterile water is the initial amount of the concentrated solution is 3mL

A sentence with the word atom

Answers

Answer:

we use atom in our sentences all the time

Explanation:

that what i put

We use atom in our sentences all the time and half the time we don’t even realize it!

Before the work of Albert Einstein and other prominent scientists of the early 1900's, the predominant view among
physicists was that light is:

Answers

A wave.

Scientists now recognize that light can behave as both a particle and a wave.

Answer:

wave

Explanation:

Why are lubricants necessary?

decrease loss of energy
reduce friction
used as fuel
increase heat energy

Answers

Answer:

reduce friction

Explanation:

Lubricants are needed to reduce the friction between two bodies in contact with one another.

Frictional force is a force that opposes the motion of a body. As a body moves forward, friction acts in an opposite direction.

Lubricants are used to reduce and remove frictionUnfortunately, without friction, motion cannot be controlled.Lubricants only reduces friction between two bodies. As friction reduces, a body moves more readily and easily.

How many moles of aluminum are equivalent to 4.816 x 1024 atoms?

Answers

Answer:

8 moles

Explanation:

To find the number of moles in a substance given it's number of entities we use the formula

[tex]n = \frac{N}{L} \\[/tex]

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

From the question we have

[tex]n = \frac{4.816 \times {10}^{24} }{6.02 \times {10}^{23} } = 8 \\ [/tex]

We have the final answer as

8 moles

Hope this helps you

Answer:

Explanation:

there are 8 moles.

A stack of 15 pennies is immersed into a 100 mL graduate initially containing 20.6 mL of water. The volume in the graduate cylinder increases to 26.0 after the pennies are added. Calculate the volume in mL of the stack of 15 pennies

Answers

Answer: 5.4

Explanation: The Law of Impenetrability says that two objects can't occupy the same space at the same time; therefore, the pennies and the water can't occupy the same space at the same time. Without the pennies the water level read 20.6 mL, dropping in the pennies gives a level of 26.0.

A liquid, solid, or gas's volume is the amount of three-dimensional space it occupies. Volume in mL of the stack of 15 pennies is  26.0 mL.

What is volume?

A liquid, solid, or gas's volume is the amount of three-dimensional space it occupies. Although there are many different units that may be used to indicate volume, the most common ones are litres, m³, gallons, milliliters, teaspoon, as well as ounces.

Due to the Law of Impenetrability, which states that two items cannot occupy the same place at the same time, neither can pennies nor water. When the pennies are added, the water level rises to 26.0 mL from 20.6 mL before.

Mass is the quantity of matter a material contains, whereas volume is indeed the space that it occupies. The density of a sample is the quantity of mass in a given volume.

Therefore, volume in mL of the stack of 15 pennies is  26.0 mL.

To learn more about volume, here:

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A drug is commercially available in capsules each containing 12.5 mg of drug and 37.5 mg of diluent. How many milligrams of additional diluent must be added to the contents of one capsule to make a dilution containing 0.5 mg of drug in each 100 mg of powder

Answers

Answer:

2450 mg

Explanation:

From the given information:

The total weight of the capsule = 12.5 mg + 37.5 mg

= 50 mg

The percentage of drug in each capsule = [tex]\dfrac{12.5}{50} \times 100[/tex]

= 25%

= 0.25

To make 0.5 mg of drug in each  100 mg of powder after dilution;

Then, the drug percent in each capsule after dilution is:

[tex]=\dfrac{0.5}{100}\times 100[/tex]

= 0.5%

= 0.005

Suppose (p) mg represent the amount that is added to the diluent in the given capsule. Then;

The total amount is = (50 + p) mg

Since the amount of the drug = 12.5 mg

Then the concentration  [tex]=\dfrac{12.5}{50 + x}[/tex] which needs to be equal to the needed concentration that is diluted.

i.e.

[tex]\dfrac{12.5}{50 + x} = 0.005[/tex]

By cross multiply;

(50 + x) 0.005 = 12.5

(50 × 0.005) + (0.005x) = 12.5

0.25 + 0.005x = 12.5

0.005x = 12.5 - 0.25

0.005x = 12.25

x = 12.25 / 0.005

x = 2450 mg

Thus, there is a need for an additional 2450 mg to make a dilution that compass 0.5 mg of drug in 100 mg powder.

A chemist adds 215.0mL of a 6.0x10^−5/mmolL mercury(II) iodide HgI2 solution to a reaction flask. Calculate the micromoles of mercury(II) iodide the chemist has added to the flask. Round your answer to 2 significant digits.

Answers

The micromoles of mercury(II) iodide : 0.013 μ moles

Further explanation

Given

215.0mL of a 6.0x10⁻⁵mmol/L HgI₂

Required

micromoles of HgI₂

Solution

Molarity(M) = moles of solute per liters of solution

Can be formulated :

M = n : V

n = moles

V = volume of solution

V = 215 mL = 0.215 L

so moles of solution :

n = M x V

n = 6.10 mmol/L x 0.215 L

n = 1.312 . 10⁻⁵ mmol

mmol = 10³ micromol

so 1.312 mmol = 1.312.10⁻⁵ x 10³ = 0.01312 micromoles ⇒ 2 sif fig = 0.013 μ moles

A pressure of 125,400 pa is equal to what kPa

Answers

Answer:

125.4 kilopascals

Explanation:

wkdje

Answer:

125,400 pa = 125.4 kPa

Explanation:

1 pa = 0.001 kPa

&

1 kPa = 1,000 pa

Which is the electron configuration of an atom in the ground state?

Answers

The configuration that corresponds to the lowest electronic energy is called the ground state. Any other configuration is an excited state. As an example, the ground state configuration of the sodium atom is 1s2 2s2 2p6 3s1, as deduced from the Aufbau principle

can u pls help me with this question ​

Answers

Answer:

I think the answer is b

Explanation:

the paragraph states, that it is an experiment to see if there is any oxygen in the water

I’m pretty sure it’s B

how does an objects mass affect its kinetic energy?​

Answers

The mass affects the kinetic energy because the more the mass the more energy is given to the object .

Please help me thank you, I will mark you?!?!?.:;)))

Answers

Answer:

a change from a solid to a liquid

Explanation:

Answer:

Dissolving salt in water is a chemical change.

Explanation:

A log burning is a chemical reaction, but not change. All the others are obviously not the answer.

To determine the mass in grams of any element, you would

a-divide the mass of a mole of the element by molar mass
b-subtract the mass of a mole of the element from Avogadro’s number
c-add the mass of a mole of the element to Avogadro’s number
d-multiply the mass of a mole by its molar mass

Answers

Answer:

d-multiply the mass of a mole by its molar mass

Explanation:

Mass of an element, Z, which is measured in grams is related to the number of moles contained in that element and its molar mass, which can be expressed using the formula:

number of moles (n) = mass ÷ molar mass

This means that the mass (in grams) can be calculated by multiplying the number of moles in the element by its molar/atomic mass. That is;

Mass (g) = number of moles (n) × molar mass (MM)

What is a spontaneous change?
A. One that occurs when one specific event happens.
B. One that occurs on its own.
C. One that has a random arrangement of particles.
D. One that has an ordered arrangement of particles.

Answers

Answer:B. One that occurs on its own

Explanation:

Choose the INCORRECT statement.
1) A molecule is a group of bonded atoms that exist as an entity.
ü) Ionic compounds result from combinations of metals and nonmetals.
iii) An anion is a positive ion.
iv) The empirical formula is the simplest formula of the ratio of atoms.
V) The molecular formula is the listing of the atoms in an actual molecule.​

Answers

Answer:

iii) An anion is a positive ion.

cuz an anion is negatively charged ion

The INCORRECT statement is "An anion is a positive ion".

So, the correct option is iii.

How an anion formed?

An atom can lose and gain one or more electrons from outermost shell which is known valence shell and formed an ions.

An atom gain one or more electrons and form negative charged species called an anion.

To learn more about an anion here.

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QUICK!! Which of the following statements is true? A. Both liquids and gases are fluids. B. Objects moving through air don't experience friction. C. Temperature is the same as heat. D. Heat is transferred in solids by convection.

Answers

Answer:

its A!! i just got finished my assignment and went straight on here because the other person didn't answer right. Trust me,its right!! good luck people<3

Explanation:

Answer:

Both liquids and gases are fluids

Explanation:

fluids are substances that flow, and gases also flow.

This is the chemical formula for nickel tetracarbonyl (a powerfully poisonous liquid used in nickel refining): A chemical engineer has determined by measurements that there are moles of nickel in a sample of nickel tetracarbonyl. How many moles of oxygen are in the sample

Answers

Answer:

38 moles of oxygen

Explanation:

This is the chemical formula for nickel tetracarbonyl (a powerfully poisonous liquid used in nickel refining): Ni(CO)₄. A chemical engineer has determined by measurements that there are 9.6 moles of nickel in a sample of nickel tetracarbonyl. How many moles of oxygen are in the sample?

Step 1: Given data

Chemical formula of nickel tetracarbonyl: Ni(CO)₄

Moles of nickel: 9.6 moles

Step 2: Establish the molar ratio of nickel to oxygen

According to the chemical formula, the molar ratio of nickel to oxygen is 1:4.

Step 3: Calculate the moles of oxygen that accompany 9.6 moles of nickel.

We will use the previously established molar ratio.

9.6 mol Ni × (4 mol O/1 mol Ni) = 38 mol O

2. How many grams of Mercury are in 9 moles of Mercury?

Answers

Answer:

hope you like my answer

Explanation:

this is the answer

can u pls help me with this question ​

Answers

Answer:

rare username has joined the meeting.

Explanation:

what is the frequency,in Hz,of electromagnetic radiation that has a wavelength of 1.25m​

Answers

Answer:

[tex]f=2x10^8Hz[/tex]

Explanation:

Hello!

In this case, given that frequency of the electromagnetic radiation showing off a wavelength of 1.25 m is computed by using the speed of light as shown below:

[tex]f=\frac{c}{\lambda }[/tex]

We plug in the wavelength and speed of light to obtain:

[tex]f=\frac{3x10^8m/s}{1.25m } \\\\f=2x10^8Hz[/tex]

Best regards!

The frequency will be "[tex]2\times 10^8 \ Hz[/tex]".

Electromagnetic radiation:

Radiation which thus travels throughout waves as well as which has both electromagnetic energy.

The power of electromagnetic radiation could range from minimum to maximum. Radio waves, radiation, x-rays, and gamma radiation are all examples of electromagnetic radiation.

Given value:

Wavelength, [tex]\lambda = 1.25 \ m[/tex]

Speed of light, [tex]c = 3\times 10^8[/tex] m/s

The frequency be:

→ [tex]f = \frac{c}{v}[/tex]

By putting the values,

     [tex]= \frac{3\times 10^8}{1.25}[/tex]

     [tex]= 2\times 10^8[/tex] Hz

Thus the above response is right.

Find out more information about wavelength here:

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Which of the following best describes the relationship between earthquakes and tsunamis?

A
An underwater earthquake can cause a tsunami.

B
Both are the result of big volcanic explosions.

C
Tsunami waves are the main cause of earthquakes.

D
Earthquakes prevent tsunamis from occurring.

Answers

Answer:

Tsunamis are usually triggered by earthquakes, volcanic eruptions and underwater explosions, landslides and other mass movements. Underseas earthquakes have generated nearly all the major tsunamis in history. Tsunamis can be generated when the sea floor abruptly deforms and vertically displaces the overlying water.

Explanation:

Answer A is correct because of the fact that tsunamis can be caused by underwater explosions

The best description that shows the relationship between earthquake and tsunami is an underwater earthquake can cause a tsunami.

The correct option is (A).

What causes tsunami?

Tsunamis are waves that form when the ocean surface moves suddenly due to earthquakes.

Some other causes of tsunami are landslides on the sea floor land collapsing into the water, massive volcanic eruptions, or a meteorite strike in the ocean.

What causes earthquake?

The displacement or collision of tectonic plates of earth lithosphere causes earthquake.

The earthquake in the sea or ocean surface leads to tsunami.

Thus, option (A) An underwater earthquake can cause a tsunami is the correct option.

Learn more about tsunami, here:

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The atomic number of nitrogen is 7. The number of electrons a neutral nitrogen atom has is
, and its atomic mass is approximately
amu.

Answers

Answer:

The number of electron in neutral atom of nitrogen are 7.

Atomic mass = 14 amu

Explanation:

An atom consist of electron, protons and neutrons. Protons and neutrons are present with in nucleus while the electrons are present out side the nucleus.

All these three subatomic particles construct an atom. A neutral atom have equal number of proton and electron. In other words we can say that negative and positive charges are equal in magnitude and cancel the each other. For example if neutral atom has 6 protons than it must have 6 electrons. The sum of neutrons and protons is the mass number of an atom while the number of protons are number of electrons is the atomic number of an atom.

The number of electron in neutral atom of nitrogen are 7.

Thus its atomic number is also 7.

Atomic mass = number of proton + number of neutron

Atomic mass = 7 + 7

Atomic mass = 14 amu

What is the correct IUPAC name for S2F8?

Answers

Answer:

Question: What Is The Correct IUPAC Name For S2F8? X ( ( (I) (IV) Di- Mono- Penta- Tetra- Tri- Hepta- Octa- Hexa- Fluorine Selenide Flourate Sulfide Sodium Sulfate Sulfur Fluoride Hydrate Acid.

How many grams of magnesium
sulfate (MgSO4) are dissolved in
0.965 L of a 0.0575 M solution?

Answers

Answer:

6.68 g MgSO₄

General Formulas and Concepts:

Math

Pre-Algebra

Order of Operations: BPEMDAS

Brackets Parenthesis Exponents Multiplication Division Addition Subtraction Left to Right

Chemistry

Aqueous Solutions

Molarity = moles of solute / liters of solution

Atomic Structure

Reading a Periodic TableUsing Dimensional AnalysisExplanation:

Step 1: Define

0.965 L

0.0575 M

Step 2: Identify Conversions

Molar Mass of Mg - 24.31 g/mol

Molar Mass of S - 32.07 g/mol

Molar Mass of O - 16.00 g/mol

Molar Mass of MgSO₄ - 24.31 + 32.07 + 4(16.00) = 120.38 g/mol

Step 3: Find MgSO₄

Substitute [M]:                     0.0575 M = x / 0.965 LIsolate x:                              0.055488 mol MgSO₄ = xRewrite:                               x = 0.055488 mol MgSO₄

Step 4: Convert

[tex]\displaystyle 0.055488 \ mol \ MgSO_4(\frac{120.38 \ g \ MgSO_4}{1 \ mol \ MgSO_4} )[/tex] = 6.67959 g MgSO₄

Step 5: Check

We are given 3 sig figs as our lowest. Follow sig fig rules and round.

6.67959 g MgSO₄ ≈ 6.68 g MgSO₄

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Answers

Answer:

Explanation:

This image is a good example of the law of conservation of mass because it shows that mass is not created or destroyed. We can see this in the picture because there's 4 hydrgen and 2 oxygen atoms in the reactants (the left side of the arrow) and there's 2 oxygen atoms and 4 hydrogen atoms in the products (right side of the arrow). Since there's the same amount of atoms on both sides, then law of conservation of mass applies.

Stealing your points like how you stole mine! +*♡

Don't answer someone's question with some nonsense and then delete it; especially when I spent over an hour on that one question. I will surely delete my answers after this and still have my 15 points...

don't reap what you sow :)

You can search that up if you don't even know what that means.

Have a nice day! +*♡

Hope this helped.

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